Preparation Of Mixed Ligand Complexes Of Cerium (III) Metal Using Multidentate Ligands And Investigation Of Their Physicochemical, Spectral, Thermal, And Antibacterial Properties.

Authors

  • J. M. Pawara
  • V. S. Kamble
  • S. S. Kamble
  • D. Y. Patil
  • H. P. Deokar
  • D. K. Patil

DOI:

https://doi.org/10.53555/jaz.v44iS8.3515

Keywords:

ligand, complexes, metal, antibacterial

Abstract

This study involves the synthesis and characterization of Cerium (III) Mixed-ligand complexes employing 2-hydroxybenzaldehyde oxime (BO) as the primary ligand and organic compounds 2-amino-3-(1H-indol-3-yl)propanoic acid (L1) , 2-amino-4-(methylthio)butanoic acid  (L2) , 2-amino-3-(4-hydroxyphenyl)propanoic acid  (L3) ,  2-Amino-3-sulfhydrylpropanoic acid  (L4) as secondary ligands. The resulting complexes exhibit a brown color and display stability, as evidenced by conductometric measurements indicating non-electrolyte behavior. FTIR analysis reveals coordination through O and N donor atoms, while thermogravimetric studies highlight stability with coordinated water molecules, supported by high decomposition temperatures. UV studies demonstrate intra-ligand and ligand-to-metal charge transfer transitions. Elemental analysis confirms a 1:2:1 ratio for the complexes. Antibacterial assays using agar cup and tube dilution methods affirm the complexes' antibacterial activity against specific bacterial strains.

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Author Biographies

J. M. Pawara

Changu Kana Thakur Arts, Commerce and Science College, New Panvel

V. S. Kamble

Changu Kana Thakur Arts, Commerce and Science College, New Panvel

S. S. Kamble

Changu Kana Thakur Arts, Commerce and Science College, New Panvel

D. Y. Patil

Karmaveer Bhaurao Patil College, Vashi

H. P. Deokar

S. D. Arts, V. S. Apte Commerce and M. H. Mehta Science College, Palghar

D. K. Patil

Changu Kana Thakur Arts, Commerce and Science College, New Panvel

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Published

2023-12-25

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